[1,1′-Bis(diphenylphosphanyl)ferrocene-κ2 P,P′]dichloridocadmium(II) dichloromethane disolvate
نویسندگان
چکیده
In the title complex, [CdFe(C(17)H(14)P)(2)Cl(2)]·2CH(2)Cl(2), the Cd(II) atom has a distorted tetra-hedral coordination geometry by two chloride anions and two P atoms of 1,1'-bis-(diphenyl-phosphan-yl)ferrocene. In the crystal, complex mol-ecules are linked into a three-dimensional network by C-H⋯Cl hydrogen bonds involving the dichloro-methane solvent mol-ecules.
منابع مشابه
[1,1′-Bis(diphenylphosphanyl)ferrocene-κ2 P,P′](η5-cyclopentadienyl)(dicyanamido-κN)ruthenium(II) dichloromethane monosolvate
The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1'-bis-(diphenyl-phosphan-yl)ferrocene] with sodium dicyanamide in dichloro-methane. The Ru(II) atom is capped by an η(5)-cyclo-penta-dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C-N-C angle of the N(CN)(2) ligand [1...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010